I did find that the ffmpeg.exe file was not active. Fixed that but still no go. Everything looks good from there, so What do you think??

So you can upload sounds and files that are over 8MB without any issues? The fact that you created a PHP.ini file with those sizes specified doesn't mean that UNA is using those settings. The best way to check is do what I explained above and see if the setting match in the Host Tools > Server Audit.
If it is picking up your php.ini settings then, you will seem something like this in the server audit:
upload_max_filesize = 103809024
post_max_filesize  =  105906176

Sounds, Files are working fine up to 99mb. No issues there.

ONLY video is not allowing anything whatsoever. I do the upload (With a 8mb video file) it works as you'd think, but once it goes back to video screen as pictured earlier, it shows that I didn't upload anything, and it says "a video is essential".